An annotated list of type specimens of 12 taxa of the genus Euphorbia (Euphorbiaceae) described from Ukraine and deposited in the National Herbarium of Ukraine (KW), the Herbarium of M.G. Kholodny Institute of Botany NAS of Ukraine, is given. The following data for each taxon are provided: original nomenclatural citation; type specimen(s) with category indicated according to protologues. In total 14 type specimens were found, including 7 holotypes, 2 isotypes, 2 lectotypes, 1 syntypes, 2 paratypes and 14 specimina authentica.
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